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Reinvestigation of the claimed oxidative addition of trans-1-bromo-2-fluorocyclohexane to trans-IrClCO(PMe3)2

✍ Scribed by Jensen, Frederick R.; Knickel, Birger


Book ID
126972132
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
275 KB
Volume
93
Category
Article
ISSN
0002-7863

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1 1,3-cis, trans-Cyclooetadiene ( 2) is an intriguing diene when considered in terms of the Diels-Alder reaction. A concerted 1,4-cycloaddition of an appropriate dienophile would give the unknown bicyclic system 2. This is to be contrasted with the possible 2 + 2 addition of the dienophile to ~ whi