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Reinvestigation of the absorption spectrum of triphenylene: Vibronic structure of the S1 ← S0 transition and location of higher excited singlet states

✍ Scribed by H. Chojnacki; Z. Laskowski; A. Lewanowicz; Z. Ruziewicz; R. Wandas

Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
342 KB
Volume
124
Category
Article
ISSN
0009-2614

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✦ Synopsis

Vibrational analysis of the absorption spectrum of triphenylene-h,, in Shpolskii matrices, supplemented by calculation of excited-state vibrations performed within the Warshel-Karplus formalism, has resulted in an Improved set of vibrations active in the S, + S,, transition. Experimental evidence and calculation of electronic transitions point to the location of the S, state at = 32000 cm-'.

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