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Reinvestigation of CuNbOF5· 4H2O

✍ Scribed by Kevin R. Heier; Kenneth R. Poeppelmeier

Book ID
102603242
Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
219 KB
Volume
133
Category
Article
ISSN
0022-4596

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✦ Synopsis

The infrared spectrum of CuNb(OH, F) 7 • 3H 2 O confirms the presence of the NbOF 2\ 5 anion. Disorder in the crystal structure of CuNbOF 5 • 4H 2 O caused misleading bond valence results and led to the assignment of the incorrect formula.

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