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Reinterpretation of charge-transfer bands observed in the electroabsorption spectra of solid aromatic hydrocarbons

โœ Scribed by Piotr Petelenz; Willem Siebrand; Marek Z. Zgierski

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
352 KB
Volume
147
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The second-derivative bands observed in the electroabsorption spectra of solid aromatic hydrocarbons are reinterpreted. The usual interpretation in terms of charge-transfer transitions can only hold in the presence of a perturbation that induces permanent dipole moments in charge transfer states. The possibility that imperfections induce such moments is investigated. Alternatively, the moments could possibly be induced by phonons.

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Multiple charge-transfer bands in the li
Multiple charge-transfer bands in the liquid-phase spectra of alkyl iodide-atomic iodine systems
โœ Robert L. Strong; Ferdinand Venditti Jr. ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 532 KB

Two bands have been rcsolvcd tn the lrcluj~-pb~~~ spcctn of transrcnt complcxo bctwccn I atoms and ~WC alkyl ioddes. lonkation potential dcpcndcncc and similarrty to compamblu vapor-phase sysfcms indiwtc the clwrgc-transfer miturc of both bands.