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Reindarstellung, NMR-Spektren und Kristallstruktur von Triphenylphosphonium-cyclobutylid, (C6H5)3PC[CH2]3

✍ Scribed by Schmidbaur, Hubert ;Schier, Annette ;Neugebauer, Dietmar


Publisher
Wiley (John Wiley & Sons)
Year
1983
Tongue
English
Weight
381 KB
Volume
116
Category
Article
ISSN
0009-2940

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The title compound has been prepared in good yield by the reaction of [Me 2 GaOMe] 3 (Me = CH 3 ) with HP(SiMe 3 ) 2 in toluene (ratio 1 : 1,1) and purified by crystallization from pentane or toluene, respectively. This organogallium compound forms (Ga±P) 3 ring skeletons with one Ga±P(SiMe 3 ) 2 ±G