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Re(I) bridged porphyrin dyads, triads and tetrads

✍ Scribed by M YEDUKONDALU; M RAVIKANTH

Book ID
107584725
Publisher
Indian Academy of Sciences,Royal Society of Chemistry
Year
2011
Tongue
English
Weight
365 KB
Volume
123
Category
Article
ISSN
0253-4134

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## Abstract A simple method has been used to synthesize four porphyrin azides with cores such as N~4~, N~3~S, N~2~SO and N~2~S~2~ in 60–90 % yields by treating the corresponding aminoporphyrins with __tert__‐butyl nitrite (__t__BuONO) and azidotrimethylsilane (TMSN~3~) in THF/CH~3~CN under mild rea