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Regulator Theory in Emulsion Polymerization. 1 I. Chain Transfer of Low Molecular Weight Mercaptans in Emulsion and Oil-Phase

✍ Scribed by Smith, W. V.


Book ID
126849916
Publisher
American Chemical Society
Year
1946
Tongue
English
Weight
721 KB
Volume
68
Category
Article
ISSN
0002-7863

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When highly reactive chain transfer agents with low water solubilities (e.g., long chain thiols) are used in emulsion polymerizations, transport of the chain transfer agent (CTA) from the monomer droplets to the polymer particles can become diffusion limited. Consequently, the concentration of CTA i