Regularities of ring-opening metathesis polymerization of cyclooctene in the presence of molybdenum catalysts
✍ Scribed by Yu. E. Begantsova; A. I. Kirillov; L. N. Bochkarev; G. A. Abakumov
- Book ID
- 106521693
- Publisher
- Springer
- Year
- 2010
- Tongue
- English
- Weight
- 179 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1573-9171
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## Abstract New nitrile‐containing polymers have been synthesized by ring‐opening metathesis polymerization of __cis__‐cyanocyclooct‐4‐ene and __cis__‐1,2‐dicyanocyclooct‐5‐ene with a 2^nd^ generation Grubbs catalyst [(H~2~IMes)(PCy~3~)Cl~2~Ru = CHPh] (H~2~IMes = __N__,__N__′‐bis(mesityl)‐4,5‐dihyd
## Abstract Rubbery thermosets prepared by ROMP of a modified castor oil containing norbornene moieties and cyclooctene have been synthesized and characterized. The thermosets range from 55 to 85 wt.‐% oil and are flexible, slightly transparent and have a sand‐like hue. Increasing concentration of