Regularities associated with the formation of lanthanide and actinide complexes
β Scribed by Richard M. Wallace
- Publisher
- Elsevier Science
- Year
- 1971
- Weight
- 64 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0020-1650
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## Abstract We present a comparative Density Functional Theory (DFT) study based on two different implementations of relativistic effects within the KohnβSham (KS) approach, to describe the metalβligand interaction in I~3~MβL complexes (L = NH~3~, NCCH~3~, CO and M = La, Nd, U). In the first model,
## Abstract Four new disulfoxideβLn^III^ complexes, [Ln(L)~2~(NO~3~)~3~]__~n~__ {Ln = La (1), __n__ = __n__; Ln = Gd (2), Dy (3) and Yb (4), __n__ = 2}, have been prepared by the reaction of Ln(NO~3~)~3~Β·__n__H~2~O with __meso__β1,3βbis(ethylsulfinyl)propane (__meso__βL) in methanol/triethylorthofo