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Regiospecific synthesis of α-(phenylthio)ketones via rhodium(II) acetate catalysed addition of thiophenol to α-diazoketones

✍ Scribed by M. Anthony McKervey; Piniti Ratananukul

Publisher: Elsevier Science
Year: 1982
Tongue: French
Weight: 177 KB
Volume: 23
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)87382-7

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✦ Synopsis

aa-Addition of thiophenol to a-diazoketones is catalysed efficiently by rhodium(I1) acetate in benzene solution at room temperature, offering a convenient regiospecific route to a variety of a-(phenylthio)ketones.

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