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Regiospecific monoalkylation of 3-butenenitrile

✍ Scribed by G.R. Kieczykowski; R.H. Schlessinger; R.B. Sulsky

Publisher
Elsevier Science
Year
1975
Tongue
French
Weight
161 KB
Volume
16
Category
Article
ISSN
0040-4039

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✦ Synopsis

We have been interested in the construction of quaternary carbon atoms bearing both a vinyl substituent and a nitrile functionality.

Compounds of this type are

πŸ“œ SIMILAR VOLUMES

The monometalation of 3-butenenitrile
The monometalation of 3-butenenitrile
✍ Shmuel Brenner; Michel Bovete πŸ“‚ Article πŸ“… 1974 πŸ› Elsevier Science 🌐 French βš– 180 KB
The cyclodimerisation of 3-methyl-2-bute
The cyclodimerisation of 3-methyl-2-butenenitrile
✍ H Tucker; G Golding; SR Purvis πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 French βš– 168 KB

3-Methyl-2-butenenitrile (1) cyclodimerised on treatment with lithium diisopropylamide in dimethoxyethane at temperatures between -78Β°C and 0Β°C to 3-amino-4-cyano-1,5,5trimethyl-1,3-cyclohexadiene (2) the structure of which was established by acid hydrolysis to the known 4-cyano-1,5,5-trimethyl-1-cy

The catalytic isomerization reactions of
The catalytic isomerization reactions of 2-methyl-3-butenenitrile into 3-pentenenitrile in ionic liquids
✍ Christophe VallΓ©e; Christine ValΓ©rio; Yves Chauvin; Gerald P Niccolai; Jean-Mari πŸ“‚ Article πŸ“… 2004 πŸ› Elsevier Science 🌐 English βš– 326 KB

The catalytic isomerization reaction of 2-methyl-3-butenenitrile (2M3BN) into 3-pentenenitrile (3PN) has been performed in the presence of Ni(0) and phosphine complexes and in biphasic ionic liquid/organic solvent. Several neutral and ionic phosphines and ionic liquids have been tested, the best res