Regiospecific fluorination of the aryl group in C6F5I and the preparation of C6F7IF2 — the first perfluorovinyl iodine (III) compound
✍ Scribed by H.J. Frohn; R. Nielinger
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 480 KB
- Volume
- 77
- Category
- Article
- ISSN
- 0022-1139
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📜 SIMILAR VOLUMES
Treating [Cp\*V(l-Cl) 2 ] 3 (Cp\* = C 5 Me 5 ) and [(2,6-i-Pr 2 C 6 H 3 N) 2 MoMe 2 ], respectively, with Me 3 SnF afforded the title compounds [Cp\*V(l-F) 2 ] 4 (1) and [(2,6-i-Pr 2 C 6 H 3 N) 2 MoF 2 ] ´THF ( 2). 1 has a tetrameric structure, in which four V atoms can be regarded as being arranged
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AgC 6 F 5 is directly and quantitatively formed from room temperature reactions of AgF and Me 3 SiC 6 F 5 in N-donor solvents, particularly EtCN. Solutions of AgC 6 F 5 prepared by this method exhibit excellent oxidative properties in reactions with a variety of groups 12 to 16 elements giving the c