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Regioselectivity of Vinyl Sulfone Based 1,3-Dipolar Cycloaddition Reactions with Sugar Azides by Computational and Experimental Studies

✍ Scribed by Sahu, Debashis; Dey, Santu; Pathak, Tanmaya; Ganguly, Bishwajit


Book ID
121856148
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
864 KB
Volume
16
Category
Article
ISSN
1523-7060

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## Abstract The reaction mechanism and solvent‐dependant regioselectivity of 1,3‐dipolar cycloaddition reactions between azide and acetylene derivatives have been studied using computational methods. The two possible reaction transition states were located. Geometry and NBO analysis found that the