In the crystal structure of the title compound, C 17 H 28 NO + ÁClO 4 À , the N-protonated piperidine ring is present in the normal chair conformation. The perchlorate anions link the cations, through intermolecular NÐHÁ Á ÁO and OÐHÁ Á ÁO hydrogen bonds, forming a chain-like structure.
Regioselectivity of reduction of 2-tert-butyl-1-benzopyrilium perchlorate
✍ Scribed by K. F. Suzdalev; A. V. Koblik
- Publisher
- Springer US
- Year
- 1989
- Tongue
- English
- Weight
- 235 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0009-3122
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📜 SIMILAR VOLUMES
In the title compound, C 26 H 36 N 2 O 3 S, the amide bearing the N-S bond has an s-cis conformation, whereas that bearing the N-tert-butyl group has an s-trans conformation, the N-N-C O torsion angles being À15.1 (2) and À174.3 (2) , respectively. The steric size of the N-tert-butyl group causes th
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The crystal structure of the title compound, C 38 H 42 N 4 O 4 S, an insect-growth regulator, has been determined. The two tertbutyl groups are in different environments and this is reflected in the 1 H NMR spectrum.