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Regioselectivity in the intermolecular Diels-Alder reaction of acyl nitroso compounds (C-nitrosocarbonyl compounds) and nitrosoformates (O-nitrosocarbonyl compounds)

✍ Scribed by Boger, Dale L.; Patel, Mona

Book ID: 121478027
Publisher: American Chemical Society
Year: 1984
Tongue: English
Weight: 286 KB
Volume: 49
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00195a057

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## Abstract The electron impact mass spectra of 2‐cyclohexen‐1‐ol and of several of its ^2^H and ^13^C labelled analogues show that the molecular ions lose a methyl radical by a completely different means from the mechanism described previously. Moreover, the retro Diels–Alder reaction also proceed