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Regioselectivity in the cyclopalladation of arylidenemethylamines (Schiff's bases)

✍ Scribed by Stanley F. Dyke; Stephen N. Quessy

Publisher
Springer
Year
1982
Tongue
English
Weight
199 KB
Volume
7
Category
Article
ISSN
0340-4285

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πŸ“œ SIMILAR VOLUMES

Aziridines-IV Catalytic decomposition of
Aziridines-IV Catalytic decomposition of phenyldiazomethane in Schiff's bases
✍ R. Bartnik; G. MlostoΕ„ πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 French βš– 714 KB

Catalytic decomposition of phenyldiazomethane in S&ill's bases is found to proceed via formation of trans-1,3dipole (azomethine ylide) as an intermediate product. Depending on the size and quantity of the substituents, the ylide undergoes either cyclization in controtatory sense to cia-aziridine or