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Regioselectivity in reaction of a dienolate with electrophiles

✍ Scribed by C.N. Lam; J.M. Mellor; P. Picard; M.F. Rawlins; J.H.A. Stibbard

Book ID: 104246176
Publisher: Elsevier Science
Year: 1978
Tongue: French
Weight: 212 KB
Volume: 19
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)95152-4

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✦ Synopsis

Preferential y-alkylation of dienolatea derived from a&unsaturated ketones is a sorely (1 needed process . Typically with allcyl halides a-alkylation2 is observed, although exceptions are known of y-alkylation 3 vith S-diaIkylamino-a@unsaturated ketones, and the y-alkylation 4

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