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Regioselective S/O substitutions in heteropolyoxothioanions: 31P NMR study and X-ray crystal structure of the half-substituted anion [(HPO4)4Mo6S3O9(OH)3]5−

✍ Scribed by Anne Dolbecq; Emmanuel Cadot; Dirk Eisner; Francis Sécheresse


Book ID
108331894
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
221 KB
Volume
300-302
Category
Article
ISSN
0020-1693

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✍ Thomas Richter; Peter Luger; Tadashi Hanaya; Hiroshi Yamamoto 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 780 KB

X-ray crystallographic analyses are reported for the two title compounds (8 and 9), of which the former crystallized in two modifications (8n and 8b). In all three structures, the pyranose rings have the %, (D) conformation and the substituents at C-l are axial and those at C-24-4 are equatorial. Th