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Regioselective Silane-Terminated Intramolecular Heck Reaction with Alkenyl Triflates and Alkenyl Iodides

✍ Scribed by Lutz F. Tietze; Andrea Modi

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
305 KB
Volume
2000
Category
Article
ISSN
1434-193X

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✦ Synopsis

One of the main problems of the Heck reaction using acyclic substrates which lead to Pd intermediates with β-and βЈ-hydrogens is the lack of selectivity in the formation of the double bond as the last step of the catalytic cycle. The use of allylsilanes as the alkene moiety permits control of the elim- [a]

📜 SIMILAR VOLUMES

ChemInform Abstract: Regioselective Sila
ChemInform Abstract: Regioselective Silane-Terminated Intramolecular Heck Reaction with Alkenyl Triflates and Alkenyl Iodides.
✍ Lutz F. Tietze; Andrea Modi 📂 Article 📅 2001 🏛 John Wiley and Sons ⚖ 29 KB 👁 1 views

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