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Regioselective ring opening by propanethiolate of (methylenedioxy)benzenes with electron-withdrawing substituents

✍ Scribed by Bruce K. Cassels; Claudemir Radetski; Marcos Caroli Rezende

Book ID: 104589457
Publisher: Elsevier Science
Year: 2010
Tongue: English
Weight: 321 KB
Volume: 111
Category: Article
ISSN: 0165-0513
DOI: 10.1002/recl.19921111006

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✦ Synopsis

Abstract

The ring opening reaction of (methylenedioxy)benzenes 1 with propanethiolate in DMF leads to products 2 and/or 3, depending on the nature of the electron‐withdrawing substituent Z.

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