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Regioselective replacement of nitro or sulfonyl group in cyclic α-(nitroalkyl)- or α-(phenylsulfonylalkyl)enones by nucleophiles

✍ Scribed by Rui Tamura; Hitoshi Katayama; Ken-ichiro Watabe; Hitomi Suzuki

Book ID: 108372150
Publisher: Elsevier Science
Year: 1990
Tongue: French
Weight: 715 KB
Volume: 46
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(01)89067-0

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New substitution reaction of allylic nit

New substitution reaction of allylic nitro compounds. Regioselective replacement of nitro group in cyclic α-(nitroalkyl)enones by nucleophiles

✍ Rui Tamura; Shinobu Tamai; Hitomi Suzuki 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 267 KB

Regioselective replacement of nitro group in cyclic c-(nitroalkyl)enones by various nucleophiles such as stabilized carbanions, amine, NaN3, PhSO2Na and PhSNa provides the overall SN2 type products.