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Regioselective Reduction of 5-Substituted 2-Alkylidene-4-oxothiazolidines by Metal Hydrides.

✍ Scribed by Rade Markovic; Marija Baranac; Milovan Stojanovic


Book ID
101968507
Publisher
John Wiley and Sons
Year
2004
Weight
103 KB
Volume
35
Category
Article
ISSN
0931-7597

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The rotational barriers between the configurational isomers of two structurally related push-pull 4-oxothiazolidines, differing in the number of exocyclic C@C bonds, have been determined by dynamic 1 H NMR spectroscopy. The equilibrium mixture of (5-ethoxycarbonylmethyl-4-oxothiazolidin-2-ylidene)-1