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Regioselective Radical Bromoallylation of Allenes Leading to 2-Bromo-Substituted 1,5-Dienes

โœ Scribed by Kippo, Takashi; Fukuyama, Takahide; Ryu, Ilhyong


Book ID
127144873
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
746 KB
Volume
13
Category
Article
ISSN
1523-7060

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๐Ÿ“œ SIMILAR VOLUMES


Metal catalysis in organic reactions. 17
โœ Anna Maria Caporusso; Federico Da Settimo; Luciano Lardicci ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 212 KB

Nickel complexes are found to be catalytically active in the cross-coupling reactions of allenic bromides with alkyl metals to give substituted allenes in excellent yields. The catalytic process proceeds generally with inversion of configuration in the allenyl moiety.