Conditions are reported which convert cycloalkenes to terminally dlfferentlated products through the intermediacy of a-alkoxy hydroperoxides. The ozonolytic cleavage of cycloalkenes in the presence of an alcohol affords a chain with an aldehyde and an a-alkoxy hydroperoxlde at the terminl. 2 We repo
✦ LIBER ✦
Regioselective ozonolytic cleavage of unsymmetric cycloalkenes
✍ Scribed by Kapa Prasad; Oljan Repič
- Book ID
- 104242441
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- French
- Weight
- 250 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0040-4039
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A recent report' on the regiospecific reactions of diepoxides with cyanocuprates and the synthetic potential for regiospecific reactions in cycloheptenes prompted us to describe our recent observations on mixed cyanocuprates. Acker' has reported that mixed cyanoalkyl cuprates regiospecifitally open