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Regioselective oxidation of internal olefins bearing neighboring oxygen functions by means of palladium catalysts. Preparation of β-alkoxy or acetoxy ketones from allyl and homoallyl ethers or esters

✍ Scribed by Jiro Tsuji; Hideo Nagashima; Kimihiko Hori


Book ID
104220929
Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
224 KB
Volume
23
Category
Article
ISSN
0040-4039

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✦ Synopsis


A new preparative method of Band y-alkoxy (acetoxy) ketones, which are important precursors of vinyl ketones and 1,4-diketones, respectively, is presented. With PdC12/CuC1/02 or PdC12/p-benzoquinone catalyst system,