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Regioselective Inter- and Intramolecular Formal [4+2] Cycloaddition of Cyclobutanones with Indoles and Total Synthesis of (±)-Aspidospermidine

✍ Scribed by Kawano, Mizuki; Kiuchi, Takaaki; Negishi, Shoko; Tanaka, Hiroyuki; Hoshikawa, Takaya; Matsuo, Jun-ichi; Ishibashi, Hiroyuki


Book ID
118751724
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
430 KB
Volume
125
Category
Article
ISSN
0044-8249

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ChemInform Abstract: Formal [4 + 2] Intr
✍ Mateo Alajarin; Angel Vidal; Fulgencio Tovar; Carlota Conesa 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 2 views

Formal [4 + 2] Intramolecular Ketenimine-Imine Cycloaddition. Synthesis of Benzimidazo[1,2-b]isoquinolines. -Formal [4+2] cycloaddition of ketenimine intermediates (V) derived from the azides (III) and diphenylketene (IV) by aza-Wittig reaction, provides the partially saturated compounds (VI). They