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Regioselective insertion of vinylidene carbene into α CH bond of aalkoxides

✍ Scribed by Toshiro Harada; Yohko Nozaki; Akira Oku

Book ID
108382375
Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
211 KB
Volume
24
Category
Article
ISSN
0040-4039

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The insertion of dicarbon (C 2) and vinylidene into methane C-H bonds was studied using ab initio molecular orbital theory. The reactions are simple models for thin film diamond growth in which C 2 is the principal growth species. The results of this study suggest that reaction of C 2 with a diamond