Regioselective hydrogen-deuterium exchange in the [B10H10]2– anion. Syntheses of [1,10-B10H8D2]2– and [2,3,4,5,6,7,8,9-B10H2D8]2–
✍ Scribed by I. B. Sivaev; P. V. Petrovskii; A. M. Filin; E. S. Shubina; V. I. Bregadze
- Book ID
- 110299672
- Publisher
- Springer
- Year
- 2001
- Tongue
- English
- Weight
- 233 KB
- Volume
- 50
- Category
- Article
- ISSN
- 1573-9171
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.003 A Ê R factor = 0.045 wR factor = 0.135 Data-to-parameter ratio = 14.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, C 19 H 15 Cl 4 NO 3 , the isoindole unit is planar and the oxazino ring adopts a twist-boat conformation. The dihedral angle between the isoindole unit and the phenyl ring is 50.46 (13) . The molecules are linked via intermolecular O-HÁ Á ÁO hydrogen bonds and weak C-HÁ Á ÁO a