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Regioselective Formation of Silylated Cyclobutenes by the Photochemical [2+2] Cycloaddition of 2(5H)-Furanones to Trialkylsilylacetylenes

✍ Scribed by Andrea D'Annibale; Maurizio D'Auria; Giovanna Mancini; Alessio Daniel Pace; Rocco Racioppi

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
555 KB
Volume
2012
Category
Article
ISSN
1434-193X

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## Abstract The photochemical behaviour of the title compound **2c** was investigated in various solvents. In benzene and __t__‐butanol photodimerization affords the __cis__‐__anti__‐__cis HH__‐ and __HT__‐dimers (H = head, T = tail). In acetonitrile, cyclohexane and 2‐propanol, photoreduction comp