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Regioselective Double Hydrophosphination of Terminal Arylacetylenes Catalyzed by an Iron Complex

✍ Scribed by Kamitani, Masahiro; Itazaki, Masumi; Tamiya, Chihiro; Nakazawa, Hiroshi


Book ID
120475329
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
557 KB
Volume
134
Category
Article
ISSN
0002-7863

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The novel, anti-Markovnikov, arylation of olefins with benzene to produce straight-chain alkylbenzenes with higher selectivity than branched alkylbenzenes is catalyzed by [Ir(-acac-O,O ,C 3 )(acac-O,O )(acac-C 3 )] 2 (acac = acetylacetonato), 1 [J. Am. Chem. Soc. 122 (2000) 7414]. The reaction of be