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Regioselective coupling of allylic ethers with ethyl 2-trimethylsilyl-3-butenoate

✍ Scribed by Yoshitomi Morizawa; Shigekazu Kanemoto; Koichiro Oshima; Hitosi Nozaki

Publisher: Elsevier Science
Year: 1982
Tongue: French
Weight: 113 KB
Volume: 23
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)87503-6

No coin nor oath required. For personal study only.

✦ Synopsis

In the presence of T1C14 the 4 position of the title s1lyl ester reacts with such electrophlles as allylic ethers or bromides carrying the leaving group on the secondary carbon without allylic rearrangement.

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