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Regioselective cleavage of aromatic methyl ethers by methanesulphonic acid in the presence of methionine

✍ Scribed by Fujii, Nobutaka; Irie, Hiroshi; Yajima, Haruaki


Book ID
127190557
Publisher
Royal Society of Chemistry
Year
1977
Weight
164 KB
Volume
20
Category
Article
ISSN
1472-7781

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Mechanism of cleavage of aromatic ethers
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Anisole solutioxmin benzene, n-hexane and carbon tetrachloride (0.1 M) was made to react with dry hydrogen chloride in presence of alumina-silica catalyst (activated by heating to 6GG'C.) containing 138 alumina. The reaction was carried out at two temperatures i.e. 140Β°C and ZOOOC. The mixture was k