✦ LIBER ✦
Regioselective additions of electrophiles to olefins remotely perturbed. The carbonyl group as a homoconjugated electron donating substituent.
✍ Scribed by Pierre-Alain Carrupt; Pierre Vogel
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- French
- Weight
- 265 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Electrophiles attack preferentiaZZy at the C(5) position of 2-norborn-5-enone and 2-bicycZo[2.2.2Joct-5-enone whereas the C(6) position is preferred for 2-chloronorbom-5-ene--2-carbonitriles and 2-chZorobicyclo[2.2.2]oct-5-ene-2-carbonit~iles.