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Regioselective Addition Reactions of Propargyl Bromides to Carbonyl Compounds with Gallium Catalyzed by Indium

✍ Scribed by Phil Ho Lee; Hyun Kim; Kooyeon Lee


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
167 KB
Volume
347
Category
Article
ISSN
1615-4150

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A Modular Approach to α-Arylated Carbony
✍ Masaharu Nakamura; Kohei Endo; Eiichi Nakamura 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 116 KB

## Abstract A modular synthesis of α‐arylated carbonyl compounds has been achieved by the combination of an indium‐catalyzed regioselective addition of β‐keto esters to conjugated diynes and a palladium‐catalyzed benzannulation reaction. Indium tris(bistriflylamide), In(NTf~2~)~3~, was found to be