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Regioselective access to tricarbonyliron complexes: controlled preparation and reactions of trifluoromethyl-substituted complexes

โœ Scribed by G.Richard Stephenson; Philip W. Howard; Stephen C. Taylor


Book ID
103224403
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
284 KB
Volume
419
Category
Article
ISSN
0022-328X

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Aldol condensation reactions of tricarbo
โœ Michel Franck-Neumann; Philippe Geoffroy; Fabien Gumery; Paul Bissinger ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 214 KB

Tricarbonyliron complexes of ฮฑ-substituted dienones are well suited starting compounds for the synthesis of diastereomerically pure 1,2,3-trisubstituted 1,3-diols of known configuration, among them 1,2,3-triols. This is achieved by aldol condensation with an aldehyde, a reaction which gives one dist