## Abstract The exposure to pentane vapour of poly(3‐alkylthiophene)s with different alkyl chains produces a modification in the optical properties of the thin films. The treatment induces a red‐shift of the electronic absorption maximum and the appearance of vibronic structure in the UV spectra. W
✦ LIBER ✦
Regioregularity in Poly(3-alkoxythiophene)s: Effects on the Faraday Rotation and Polymerization Mechanism
✍ Scribed by Guy Koeckelberghs; Marnix Vangheluwe; Kim Van Doorsselaere; Elke Robijns; André Persoons; Thierry Verbiest
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 148 KB
- Volume
- 27
- Category
- Article
- ISSN
- 1022-1336
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✦ Synopsis
Abstract
Summary: Poly(3‐alkoxythiophene)s with different degrees of regioregularity were prepared using three different methodologies. It is shown that their Faraday rotation is highly dependent on the degree of regioregularity. The origin of the differences in regiospecificity of the methodologies is discussed.
Structure of the polymer pol 3.
magnified imageStructure of the polymer pol 3.
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