✦ LIBER ✦

Regiocontrolled synthesis of the ergosterol B-isomers

✍ Scribed by Roland E. Dolle; Stanley J. Schmidt; Lawrence I. Kruse

Book ID: 104216535
Publisher: Elsevier Science
Year: 1988
Tongue: French
Weight: 117 KB
Volume: 29
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)80358-5

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✦ Synopsis

Summarv: A novel, regiocontrolled synthesis of the ergosterol B-isomers, (1). ( 2) and (3) is described, the success of which was realized via the highly regioselective formation of intermediate trienoltriflates. (2). ( 8) and ( 9).

An intriguing problem of long standing interest in steroid chemistry is the regiospecific preparation of the ergosterol B-isomers, B,, B3 and B2, identified

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