✦ LIBER ✦
Regiocontrol in the intramolecular silyl modified sakurai (ISMS) reaction. An efficient synthesis of a Dacus oleae fruit fly pheromone.
✍ Scribed by István E. Markó; Abdelaziz Mekhalfia
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- French
- Weight
- 248 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
The ISMS reaction, which initially afforded a mixture of regioisomeric olefins, can now be controlled to produce only the exocyclic alkene. The ISMS methodology was used in a highly efficient synthesis of a Dacus oleae pheromone 8.