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Regiochemical control in the Diels-Alder reactions of substituted naphthoquinones. Model studies on a regiospecific approach to adriamycinone

✍ Scribed by Kelly, T. Ross; Gillard, John W.; Goerner, Richard N.; Lyding, Judith M.

Book ID
120257938
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
263 KB
Volume
99
Category
Article
ISSN
0002-7863

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Regiochemical control in the diels-alder
Regiochemical control in the diels-alder reactions of substituted naphthoquinones: orientation in the synthesis of benz[a]anthraquinones
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The regioselectivity in the Diels-Alder reactions of styrene with certain substituted 1,4-naphthoquinones was explored. The results were consistent with predictions based upon analysis of dione polarization. We have extended the general Diels-Alder reactions between styrenes and naphthoquinones that

Regiochemical control in the diels alder
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✍ T.Boss Kelly πŸ“‚ Article πŸ“… 1978 πŸ› Elsevier Science 🌐 French βš– 261 KB

In conjunction with ongoing studies directed toward the development of a regiospecific synthesis of adriamycin, we recently advanced' a rationale for the regiochemical outcome of Diels Alder reactions between unsymmetric dienes and some oxygenated naphthoquinones. We now report the result of additio