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Regiochemical Control by Remote Substituents — A Selective Synthesis of Angularly Fused Ring Systems.

✍ Scribed by George A. Kraus; Ning Zhang; Jing Qiang Wei; Jan H. Jensen


Publisher
John Wiley and Sons
Year
2005
Weight
26 KB
Volume
36
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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✍ He-Ping Wu; Rudolf Aumann; Roland Fröhlich; Birgit Wibbeling 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 295 KB 👁 2 views

An efficient pathway for the stereocontrolled synthesis of functionalized, angularly fused tricyclic ring systems from readily available (1-alkynyl)carbene complexes [(OC) 5 M C(OEt)-CCR] (M Cr, W; R Ph, c-C 6 H 9 ) is described. The synthesis involves the formation of a 1-metalla-1,3,5-hexatriene f