Regio- and Stereoselective Synthesis of Aminoinositols and 1,2-Diaminoinositols from Conduritol B Epoxide.
β Scribed by Pedro Serrano; Amadeu Llebaria; Antonio Delgado
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 8 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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Regio-and Stereospecific Synthesis of (O-TIPS)-Protected 2-Hydroxyalkylmercaptans from Epoxides and Triisopropylsilanethiol. -Epoxides undergo a regio-and stereospecific ring-opening with triisopropylsilanethiol (II) and DBU to provide silyloxythiols highly selectively. Desilylation can be achieved
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