๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Regio- and stereoselective ring opening of epoxy alcohols with organoaluminium compounds leading to 1,2-diols

โœ Scribed by Toshifumi Suzuki; Hiroyuki Saimoto; Hiroki Tomioka; Koichiro Oshima; Hitosi Nozaki

Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
239 KB
Volume
23
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

โœฆ Synopsis

Financial support by the Ministry of Education, Science, and Culture, Japanese Government (Grant-in-Aid #56430027) is acknowledged.

๐Ÿ“œ SIMILAR VOLUMES

Ring-opening of epoxyalcohols by diethyl
Ring-opening of epoxyalcohols by diethylaluminium cyanide. Regio- and stereoselective synthesis of 1-cyano-2,3-diols
โœ Fabio Benedetti; Federico Berti; Stefano Norbedo ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 211 KB

Diethylaluminium cyanide is a highly selective reagent for the ring opening of 2,3-epoxyalcohols under mild conditions; the reaction takes place at C-3, with inversion of configuration, to give 1-cyano-2,3-diols.

Ring opening of 2,3-epoxy 1-tosylates to
Ring opening of 2,3-epoxy 1-tosylates to halohydrins and subsequent elaboration to asymmetrical alcohols
โœ Chiara Federici; Giuliana Righi; Leucio Rossi; Carlo Bonini; Lucia Chiummiento; ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 273 KB

Aiwactz 2.3 epoxy alcohols-1.tosylates are regio and chemoselectively opened to the corresponding 3-halohydrins (I, Br, Cl): the reduction of the iodohydrins to the moaopmkcted dials aad subsequent standard coupling of the tosyl pup