Regio- and stereoselective reductive opening of diene-ester derived monoepoxides with palladium catalyst and dimethylamine–borane complex

✍ Scribed by Hervé David; Laurent Dupuis; Marie-George Guillerez; François Guibé

• Book ID: 104210207
• Publisher: Elsevier Science
• Year: 2000
• Tongue: French
• Weight: 140 KB
• Volume: 41
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)00380-4

✦ Synopsis

Monoepoxides of diene-esters are regio-and stereoselectively reduced to homoallylic alcohols by dimethylamine-borane complex in the presence of acetic acid and catalytic amounts of Pd(PPh 3 ) 4 .