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Regio- and Stereoselective Oxidation of Ene-Type Chlorinated Olefins

✍ Scribed by Suzuki, Shigeaki; Onishi, Takashi; Fujita, Yoshiji; Otera, Junzo

Book ID
120239010
Publisher
Taylor and Francis Group
Year
1985
Tongue
English
Weight
228 KB
Volume
15
Category
Article
ISSN
0039-7911

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2,4-Dioxopentane-3-thione 1a reacts as an enophile with ethers or allenes as ene counterparts, the formation of the thiophilic adduct is followed by a fast cycloaddition reaction various allyl derivatives affording thiophilic ene adducts as single regioisomers with high (E) stereoselectivity. Using