Regio- and Stereoselective Lithiation of 2,3-Diphenylaziridines: A Multinuclear NMR Investigation
β Scribed by Capriati, Vito; Florio, Saverio; Luisi, Renzo; Mazzanti, Andrea; Musio, Biagia
- Book ID
- 127182105
- Publisher
- American Chemical Society
- Year
- 2008
- Tongue
- English
- Weight
- 423 KB
- Volume
- 73
- Category
- Article
- ISSN
- 0022-3263
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## Abstract By means of ^27^Al, ^1^H, ^17^O and ^13^C NMR spectroscopy the structure of the methylaluminoxane (MAO) cocatalyst of KaminskyβSinn catalysts was investigated. We have found that the ^27^Al NMR resonance line of MAO is extremely broad at room temperature (Ξ΄ β 60, ΞΟ~1/2~ 50 Β± 10 kHz). A
Methyl B-D-arabinopyranoside (1) has been stereoselectively aeuterated, by the Treatment of deuteratgd Raney Ni in D 0, to give the 2,3.4-trideutereo-8-D-arabinopyranoside 2 in 33% yield. f t was then converted to 3.4-IsoproFylidene derivative Tb in 90% yield and subsequently derivatired to 2-D-phen