𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Regio- and Stereoselective Carbobismuthination of Alkynes

✍ Scribed by Dr. Yoshihiro Nishimoto; Midori Takeuchi; Dr. Makoto Yasuda; Prof. Dr. Akio Baba

Book ID
111999431
Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
382 KB
Volume
124
Category
Article
ISSN
0044-8249

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Regio- and stereoselective hydrosilylati
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✍ Palle J. Pedersen; Jonas Henriksen; Charlotte H. Gotfredsen; Mads H. Clausen 📂 Article 📅 2008 🏛 Elsevier Science 🌐 French ⚖ 277 KB

Regio-and stereoselective hydrosilylation of terminal alkynes on solid support using diisopropyl hydrosilanes yielding b-(E)-vinyl silanes with excellent selectivity is reported. The hydrosilylation is catalyzed by Pt(DVDS)/P( i BuNCH 2 CH 2 ) 3 N (DVDS = 1,3-divinyl-1,1,3,3-tetramethyl-disiloxane),