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Regio- and stereoselective addition of selenium dihalogenides to propargyl halogenides

✍ Scribed by S. V. Amosova; M. V. Musalov; A. V. Martynov; V. A. Potapov


Book ID
111461035
Publisher
Springer
Year
2011
Tongue
English
Weight
151 KB
Volume
81
Category
Article
ISSN
1070-3632

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ChemInform Abstract: Preparation of Trib
✍ Shinichi Usugi; Jun Tang; Hiroshi Shinokubo; Koichiro Oshima πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 30 KB πŸ‘ 1 views

Preparation of Tributylstannylmanganate and Its Addition to Propargylic Alcohols with High Regio-and Stereoselectivities. -Reaction of 4 equiv. MeLi with MnCl 2 generates Me 4 MnLi 2 which adds to R 3 Sn-SnR 3 to give a solution of stannylmanganates in almost quantitative yield. These reagents [cf.