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Regio- and Stereoisomeric Control of the Aggregation of Zinc-chlorins Possessing Inverted Interactive Hydroxyl and Carbonyl Groups

✍ Scribed by Yagai, Shiki; Miyatake, Tomohiro; Tamiaki, Hitoshi


Book ID
126273382
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
171 KB
Volume
67
Category
Article
ISSN
0022-3263

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Self-aggregation of synthetic zinc chlor
✍ Hitoshi Tamiaki; Tomohiro Miyatake; Rikuhei Tanikaga πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 212 KB

Zinc 3-acetyl-131-hydroxychlorin Zn-4 was efficiently prepared as a model for naturally occurring bacteriochlorophyil-d possessing 3t-hydroxyl and 13-keto groups. Synthetic model Zn-4 self-aggregates to form oligomers in non-polar organic solvents as well as the isomeric zinc 31-hydroxy -13~-oxochlo