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Regio- and stereochemistry of the intramolecular [2+2] photoproducts from two related vinylogous imides

✍ Scribed by Charles S. Swindell; S.Jane deSolms; James P. Springer


Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
252 KB
Volume
25
Category
Article
ISSN
0040-4039

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✦ Synopsis


The regio-and stereochemistry of the intramolecular [2+2] photoproducts from two related vinylogous imides have been determined with the aid of X-ray crystallography; their chemistry and a mechanistic rationale of their formation are presented.


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Conformation of the tripeptide Cbz-Pro-L
✍ Régis Millet; Laurence Goossens; Jean-François Goossens; Philippe Chavatte; Kari 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 895 KB

## Abstract Chemical modifications of dual NK~1~/NK~2~ ligand Cbz‐Gly‐Leu‐Trp‐OBzl(CF~3~)~2~ (1) enabled us to create a high NK~1~ selective ligand Cbz‐Pro‐Leu‐Trp‐OBzl(CF~3~)~2~ (2). A determination of the conformational behavior of tripeptide 2 in solution is described. The 1D and 2D ^1^H‐NMR tec