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Regio- and stereo-control in the rhodium catalysed hydroformylation of some alkenylphosphines

✍ Scribed by W.Roy Jackson; Patrick Perlmutter; E.Elizabeth Tasdelen


Book ID
111714404
Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
121 KB
Volume
31
Category
Article
ISSN
0040-4039

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The rhodium catalysed reactions of N-allyl-and N-butenyl-l,3-diaminopropanes give single products arising from exclusive hydroformylation at the terminal carbon when the hindered bisphosphite ligand, BIPHEPHOS is used. Reactions using a high carbon monoxide : hydrogen ratio (9 : I) and triphenylphos